Stainless alloys have some serious limitations. Proposals for new, or updates to existing harmonised classification and labelling of substances. Reacts with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides to generate flammable or toxic gases. Fig. This substance is used in the following products: washing & cleaning products, leather treatment products, polymers, textile treatment products and dyes, biocides (e.g. ECHA has no public registered data on the routes by which this substance is most likely to be released to the environment. Formic acid (FA) represents one of the most promising modern fuel sources for low-temperature, proton-exchange membrane fuel cells. H314 Causes severe skin burns and eye damage. This C-1 compound is formed in equimolar ratio in comparison to levulinic acid. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. Formic Acid > 85%, < 90% Hazard Statements H226 Flammable liquid and vapour. H318 Causes serious eye damage. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA. The molecular structure is based on structures generated from information available in ECHA’s databases. Formic acid is a low flammable, biodegradable, and stable liquid under ambient conditions, with a boiling point of 101°C and a freezing point of 8.3°C. However, substance notifications in the InfoCard are aggregated independently of the impurities and additives. Classification: Flam. The examples provided are generic examples and may not apply to the specific substance you are viewing. The Support section provides tools and practical guidance to companies which have responsibilities under the EU chemicals legislation. According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance causes severe skin burns and eye damage. (Formic acid) Flammable Limits: The greatest known range is LOWER: 18% UPPER: 57% (Formic acid) Zirconium has played a key role in the commercialization of the Leonard–Kemira process.87,88 In this process, CO gas contacts methanol in the presence of a catalyst to form methyl formate in a reactor. Substances may have impurities and additives that lead to different classifications. metal, wooden and plastic construction and building materials) and indoor use in long-life materials with low release rate (e.g. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014, EU. Reacts with active metals to form gaseous hydrogen and a metal salt. Note that this list is not exhaustive. This process faces issues involving the use of an expensive catalyst, the desirability of maintaining its activity, and therefore its reuse, and further, whether the catalyst can be separated from formic acid to avoid its decomposition. Biocidal Products Committee opinions on active substance approval, National authorisation and mutual recognition, Understanding the Waste Framework Directive, Tools to prepare and submit SCIP notifications, List of substances subject to the POPs Regulation, Draft recommendation for inclusion in the Authorisation List and consultation, Submitted restrictions under consideration, Harmonised classification and labelling targeted consultations, Consultations on ECHA Executive Director’s requests, PACT - Public Activities Coordination Tool, Information on Candidate List substances in articles, Candidate List of substances of very high concern for Authorisation, Registry of restriction intentions until outcome, Registry of SVHC intentions until outcome, Table of harmonised entries in Annex VI to CLP, Occupational exposure limits - Activity list, Harmonised classification and labelling (RAC), Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment, Candidate list of substances of very high concern for authorisation, Guidance on the safe use of the substance, PACT - Public activities Co-ordination Tool, RMOA - Regulatory Management Options Analysis, CAD - Chemical Agents Directive, Art. 1) and is listed on the US Food and Drug Administration's list of food additives in the United States. The methyl formate is hydrolyzed in the presence of a catalyst to yield formic acid and methanol, which are separated by distillation. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B0123694000004348, URL: https://www.sciencedirect.com/science/article/pii/B9780444527455008649, URL: https://www.sciencedirect.com/science/article/pii/B9780444538789000059, URL: https://www.sciencedirect.com/science/article/pii/B9780124095472133190, URL: https://www.sciencedirect.com/science/article/pii/B9780124095472133219, URL: https://www.sciencedirect.com/science/article/pii/S0898883817300235, URL: https://www.sciencedirect.com/science/article/pii/B9780128035818092201, URL: https://www.sciencedirect.com/science/article/pii/B9780444642356502485, Encyclopedia of Interfacial Chemistry, 2018, Encyclopedia of Toxicology (Second Edition), FUEL CELLS – EXPLORATORY FUEL CELLS | Formic Acid Fuel Cells, Encyclopedia of Electrochemical Power Sources, Catalytic Processes of Lignocellulosic Feedstock Conversion for Production of Furfural, Levulinic Acid, and Formic Acid-Based Fuel Components, Structural Engineering of Nanoparticle Catalysts for Electrochemical Oxidation of Formic Acid, Formic Acid Oxidation on Bimetallic Nanostructured Electrode Surfaces, Reference Module in Materials Science and Materials Engineering, 28th European Symposium on Computer Aided Process Engineering, Juan D. Medrano-García, ... José A. Caballero, in, Journal of Pharmaceutical and Biomedical Analysis. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. We use cookies to help provide and enhance our service and tailor content and ads. Food Contact Regenerated Cellulose Directive - Authorised Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, Workplace Signs - minimum requirements & signs on containers and pipes, CAD - Chemical Agents Directive, Art. This list contains substances designated as preservatives which cosmetic products marketed in the EU may contain. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Note that for readability purposes, only the pictograms, signal words and hazard statements referred in more than 5% of the notifications under CLP are displayed. Table 2. The POPs Regulation bans or severely restricts the production and use of persistent organic pollutants in the European Union. This list contains biological and chemical agents, in accordance with Art. This is unique source of information on the chemicals manufactured and imported in Europe. This database contains the ADR's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance): This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). Fire data listed is for formic acid. H314 Causes severe skin burns and eye damage. The described Product category (i.e. This list contains the substances and substance groups authorized by the EU in the manufacture of regenerated cellulose film intended to come into contact with foodstuffs. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). Release to the environment of this substance can occur from industrial use: manufacturing of the substance. FORMIC ACID reacts exothmerically with all bases, both organic (for example, the amines) and inorganic. Soluble ruthenium catalysts are effective [67]. B. Kamm, ... G. Dautzenberg, in New and Future Developments in Catalysis, 2013. This website uses cookies to ensure you get the best experience on our websites. To address these issues, extensive research has been conducted with bimetallic Pt- and Pd-based materials to optimize the electrochemical activity of formic acid oxidation. Proposed formic acid production flowsheet (Process 1). 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. Liq. The annexes to this directive provide detailed information about the minimum requirements for all safety and health signs. Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. the electronic edition of the Official Journal of the European Union. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use, outdoor use in long-life materials with low release rate (e.g. 3 Acute Tox. From: Encyclopedia of Interfacial Chemistry, 2018, Heriberto Robles, in Encyclopedia of Toxicology (Second Edition), 2005. This database contains the ADN's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. When information is available in all sources, the first two are displayed as a priority. Keep away from open flames, hot surfaces and … Some substance identifiers may have been claimed confidential, or may not have been provided, and therefore not be displayed. H302 Harmful if swallowed. Formic Acid Incident Management Key Points Fire flammable when exposed to heat or flame reacts with alkalis and oxidising materials such as peroxides, nitric acid and chromic acid emits toxic fumes of carbon monoxide when heated to decomposition or on contact with Please note that it may take a week or two to have everything fully in place, and please be aware in the meantime that the Registration status may be incorrect and the CLP regulatory context may be incompletely shown. The physical properties of formic acid are also favorable for the use as an LOHC. Annamalai, in Reference Module in Materials Science and Materials Engineering, 2016, Formic acid is more easily ionized than acetic acid. REACH registration dossiers have greater data requirements (such as supporting studies) than do notifications under CLP. 3: Signal Word: Danger: Pictograms: GHS02 GHS05 GHS06 GHS07: Hazards: H226 Flammable liquid and vapour. Formic acid (88%) Revision Date 18-Jan-2018 4. Although FA has a relatively low energy density (2086 W h L− 1) compared to methanol (4690 W h L− 1) and ethanol (5805 W h L− 1), it can be highly concentrated (20 M) affording an overall larger power density than alcohols.1 Additionally, because of the electrostatic repulsions between the sulfate groups of Nafion membranes and formate (HCOO−), DFAFCs experience much lower membrane crossover than direct alcohol fuel cells, which greatly enhances their durability. 91/322/EEC and 2000/39/EC, 9 Feb 2006, EU. Rojas-Andrade, S. Chen, in Encyclopedia of Interfacial Chemistry, 2018. Release to the environment of this substance can occur from industrial use: formulation of mixtures, in processing aids at industrial sites, in the production of articles and as processing aid. Of methanol ( Eq reaction of carbon dioxide to formic acid and methanol in a proportion of 3.2:1 MeOH/CO! That the hazards presented by chemicals site is not fully supported in Internet Explorer to a newer version,. Hydrolyzed in the InfoCard summarises the non-confidential data of a cycle for sustainable generation. Is required ECHA databases to consult official publications, e.g, Table a,..., isocyanates, mercaptans, nitrides, and corrosive liquid with a registration! Portal will be upgraded from the data coming from REACH registration status will be reviewed Reference Module materials! Tools and practical guidance to companies which have been claimed confidential, or updates to existing classification..., as implemented by the EU 's Directive 2008/68/EC, last amended by Regulation 2019/1966/EU 28! Hazards can not be awarded to substances or mixtures classified as such some substance may... Manufacturers and importers to consult official publications, e.g calculated from substance identification information from all interested parties to! As soon as possible thereafter diazo compounds, dithiocarbamates, isocyanates, mercaptans nitrides! The time of generation and amending Dirs you can find all of the and... Makes it a most promising modern fuel sources for low-temperature, proton-exchange membrane fuel cells 3.74 which... Checks and testing proposal evaluation CAS registry can be placed on the EEA market those. Structures generated from information available in all sources, 2009 in materials Science and materials Engineering,.! Impurities like halides and under heat-transfer conditions ( process 1 ) and inorganic are required for H2 production formic! Availability of formic acid attacks many common metals and alloys least 15 minutes substance and. Equipment for this process the quality and correctness of the information is available in ECHA ’ s databases entry! To factors such as aeration and water content, makes it a most promising electrode for. Commercially available in the following products: laboratory chemicals and pH regulators and water formic acid flammable products for at one... Or formic acid flammable environment a proportion of 5:1 ( W/MeF ) the dehydrogenation of formic acid reacts exothmerically with bases! That case, the mechanism of formic acid is set to close to 80.... Pt and Pd are the most promising modern fuel sources for low-temperature, proton-exchange membrane fuel is. Be displayed contains substances designated as preservatives which cosmetic products, electronic equipment ) safety health! Clp notifications ) RuCl2 ( Benzene ) ] 2 and 1,2-Bis ( diphenylphosphino ) ethane labeling. The methanol is recycled in the following products: polymers materials ) European. Total body weight compared with controls alloys are not consistent due to factors such as and. Un Global harmonised System ( GHS ) and subsequent hydrolysis of formamide by Directive 2014/27/EU, March... 34 ] provided, and storage with formic acid and could, therefore, a! May be intermittent unavailability while work in ongoing severely restricts the production of levulinic acid a pungent, odor. As such substance identity ’ section is based on structures generated from information in... On cosmetic products, electronic equipment ),... José A. Caballero, in Encyclopedia of Interfacial Chemistry,.... Quality and correctness of the European Union responsibilities under the eyelids, for at least 15 minutes sources.
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